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Most
commonly used in heating elements, MoSi2 is finding a wider range
of uses suited to its properties.
Heating
Elements
Because of its ability to reach high temperature, MoSi2 elements
are widely used in glass production. They are also often utilized
in advanced ceramics applications, and can be found heating small
furnaces for Research and Development testing, as well as large
production furnaces. Many different styles of furnace are available
for a wide range of applications. In a heater element, MoSi2 withstands
oxidation at high temperatures because a protective siliceous coating
forms on the surface.
High
Temperature Structural Applications
MoSi2 has been investigated for use in high temperature structural
applications. It appears to show promise in this area, with its
high melting point and moderate density. Work has been going on
since the early 1990s to develop composites which overcome the two
main difficulties, low toughness at low temperatures and high creep
rates at high temperatures. Several possible uses for such materials
have been suggested; for example turbine airfoils, missile nozzles
and industrial gas burners.
Aerospace
Applications
During the 1950's the National Advisory Committee for Aeronautics
(NACA) carried out a series of experiments on MoSi2 relating to
flight applications.
Work
had begun on a nuclear powered aircraft in the 1940s, in the both
the United States and the Soviet Union. The US project was cancelled
by President Kennedy in 1961, due to the fact that about $1billion
had been spent over 15 years, and the likelihood of ever producing
such an aircraft was still remote. A 1953 NACA report considers
the possible use of Molybdenum Disilicide Fuel elements for an air-cycle
nuclear reactor. The report concluded that MoSi2 was suitable for
this use.
In
1958, it was investigated as a coating for molybdenum parts for
use in a supersonic heated-air jet, where its thermal properties
protected the molybdenum for 470 seconds at 3,100F. An uncoated
model was virtually destroyed in less than 6 seconds.
Research
in MoSi2 as a potential aircraft component has been used in more
recent times. In the late 1990s, MoSi2 composites were investigated
at Lewis Research Center, Cleveland, Ohio as a potential material
for aircraft engine components. Currently, these are made from nickel
based super alloys. The most promising composites contained Si3N4
particles. Although MoSi2 exhibits many of the same properties as
the super alloys, the low fracture toughness and high creep referred
to earlier in this article have to be overcome before it can be
used successfully in this application. A further problem, that of
pesting, where the substance disintegrates into powder due to increased
oxidisation, also needed to be solved. Finding the correct ration
of Si3N4 to MoSi2 appears to have overcome all of these obstacles.
It has the effect of doubling room-temperature hardness and results
in the formation of a protective Si2ON2 scale that resists pesting.
Furthermore, high temperature creep strength is almost 105 times
that of pure MoSi2.
Pyrolitic
Paint
MoSi2 can be used as a conductor in a pyrolytic paint - that is
a paint which generates heat when an electrical current is applied.
On the 15 October 2003, Oki Electric issued a press release announcing
a new product of this type. The main advantage of this type of paint
is it replaces metal plate heat sinks in electrical equipment. When
applied to components, it dissipates heat via conduction and radiation.
It allows for the manufacture of smaller units, and could be used
in any device that currently employs a heat sink, for example lighting
and automobiles.
Ion
Emitting Hairdryer
On October 28th 2003, a US patent was granted for an Ion emitting
hot air blower. This is for use in a hairdryer, where it is claimed,
the positive ions promote grooming and rapid drying of the user's
hair. The heating element is made from MoSi2, which it is claimed
produces a large amount of positive ions when heated.
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